Navel protonic conductive silicates produced by the sol-gel method

Citation
Sm. Jones et al., Navel protonic conductive silicates produced by the sol-gel method, J DISP SCI, 21(1), 2000, pp. 97-117
Citations number
58
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
ISSN journal
01932691 → ACNP
Volume
21
Issue
1
Year of publication
2000
Pages
97 - 117
Database
ISI
SICI code
0193-2691(2000)21:1<97:NPCSPB>2.0.ZU;2-X
Abstract
Materials which display ionic conductivity were produced by the sol-gel and microemulsion-gel methods. The charging and discharging characteristics we re investigated and it was found that a single ionic species was responsibl e for the conduction, the ionic species being residual protons from the ini tial component mixture. The complex impedence of various samples was measur ed and the ionic conductivities ranged in value from 9 X 10(-8) to 1 X 10(- 5) ohm(-1)cm(-1). An Arrhemius plot for a microemulsion-gel revealed that t he energy of activation was 0.15 eV.