LOCAL prediction with near infrared multi-product databases

Citation
P. Berzaghi et al., LOCAL prediction with near infrared multi-product databases, J NEAR IN S, 8(1), 2000, pp. 1-9
Citations number
9
Categorie Soggetti
Agricultural Chemistry","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF NEAR INFRARED SPECTROSCOPY
ISSN journal
09670335 → ACNP
Volume
8
Issue
1
Year of publication
2000
Pages
1 - 9
Database
ISI
SICI code
0967-0335(2000)8:1<1:LPWNIM>2.0.ZU;2-5
Abstract
This study evaluated the use of an algorithm (LOCAL) for local calibration using multi-product databases. Four different databases were used: forages (hay, corn silage, haylage, small grain silage and total mixed ration; n = 2924), grain (barley, corn, oats and wheat; n = 1464), meat (meat and bone meal, fish meal and poultry meal; n = 693) and feed (bakery products, mixed feed, poultry feed and soya products; n = 1518), One-tenth of the samples were selected for validation from each database. Predictions of validation samples using generic and specific global calibrations were compared to the predictions generated by LOCAL. Standard errors of prediction for LOCAL ca librations were always lower than those of generic global calibrations and similar to those of specific global calibrations. However, LOCAL prediction s were further improved by using different settings for each constituent. T he analysis of the samples selected by LOCAL showed that for heterogeneous products such as total mixed rations and corn silage, LOCAL optimised predi ctions by choosing samples from different products. LOCAL calibration was t hen used with one database (n = 6599) comprising all the samples. Standard errors of prediction were similar to those obtained with the four different databases. LOCAL can accurately predict the composition of different produ cts using multi-product databases. Routine analysis can be simplified by us ing LOCAL calibration combined with large databases. in addition, LOCAL can provide accurate predictions of spectra from remote standardised instrumen t without the operator identifying the sample.