Dynamic thermal expansivity near the glass transition

Citation
C. Bauer et al., Dynamic thermal expansivity near the glass transition, J NON-CRYST, 262(1-3), 2000, pp. 276-281
Citations number
25
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF NON-CRYSTALLINE SOLIDS
ISSN journal
00223093 → ACNP
Volume
262
Issue
1-3
Year of publication
2000
Pages
276 - 281
Database
ISI
SICI code
0022-3093(200002)262:1-3<276:DTENTG>2.0.ZU;2-E
Abstract
Dielectric techniques were used to investigate the thermal expansivity of p olystyrene films. Capacitive scanning dilatometry (CSD) employs temperature ramping in order to monitor the non-linear structural relaxation in the gl ass transformation range and to quantify liquid fragility. In the linear re sponse regime, the complex thermal expansivity is obtained as a function of the temperature cycling frequency and is observed to reflect the structura l relaxation. (C) 2000 Elsevier Science B.V. All rights reserved.