Lead-antimony alloys with a wide range of Sb contents, pure Pb and pure Sb
were subjected to sulfuric acid solutions to elucidate their electrochemica
l characteristics by cyclic voltammetry and corrosion potential measurement
s. A corrosion test with a Pb/Sb galvanic couple was also done. For Pb-rich
alpha-phase alloys (< 0.3 wt.% Sb), their electrochemical behavior was sim
ilar to that of pure Pb. On the other hand, for alpha + beta phase alloys (
> 0.3 wt.% Sb) their behavior was quite different from those of alpha-phase
alloys; (i) dissolution current of Sb was proportional to Sb contents; (ii
) hydrogen overvoltage was decreased remarkably with increasing the Sb cont
ents; (iii) the corrosion potential shifted and approached that of pure Sb
with time. It is confirmed that the electrochemical behavior of Pb-Sb alloy
s is related to the electrochemical property of the individual phase involv
ed in the internal galvanic couples formed. (C) 2000 Elsevier Science S.A.
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