Distribution of the Pb and Sb atoms in the (Pb, Sb)S layers of the Franckeite-type misfit compound [(Pb, Sb)S](2.28)NbS2 examined by scanning tunneling and atomic force microscopy
H. Bengel et al., Distribution of the Pb and Sb atoms in the (Pb, Sb)S layers of the Franckeite-type misfit compound [(Pb, Sb)S](2.28)NbS2 examined by scanning tunneling and atomic force microscopy, J SOL ST CH, 149(2), 2000, pp. 370-377
The distribution of the Pb and Sh atoms in the (Pb, Sb)S layers of the misf
it compound [(Pb, Sb)S](2.28)NbS2 was investigated by scanning tunneling mi
croscopy (STM) and atomic force microscopy (AFM), This compound has NaCl-ty
pe MS (M = Pb, Sb) layers (Q-layers) alternating with NbS2 layers (H-layers
) in which the Nh atoms are located in slightly distorted trigonal prism si
tes. Both the H- and Q-layers of [(Pb,Sb)S](2.28)NbS2 were imaged by STM an
d AFM. The atomic-scale STM and AFM images were analyzed in terms of the pa
rtial and total electron density plots calculated for the Q- and H-layers,
The STM images of the Q-layers allowed us to detect all the constitutive at
oms of the Q-layers with a short-range ordering of pure Pb and Sb rows in t
he a(Q) modulation direction. (C) 2000 Academic Press.