Citation
Y. Xie et al., A mild one-step solvothermal route to metal phosphides (metal = Co, Ni, Cu), J SOL ST CH, 149(1), 2000, pp. 88-91
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
ISSN journal
00224596
→ ACNP
Volume
149
Issue
1
Year of publication
2000
Pages
88 - 91
Database
ISI
SICI code
0022-4596(200001)149:1<88:AMOSRT>2.0.ZU;2-1
Abstract
Nanocrystalline Co2P Ni2P, and Cu3P were successfully prepared through a si
mple solvothermal process based on the direct reactions of metal halides wi
th yellow phosphorus at rather mild temperatures (80-140 degrees C) with et
hylenediamine used as the solvent, XRD, XPS, and TEM were used to study the
phases, compositions, and morphologies of the final products, A possible m
echanism is proposed and the influential factors in the process are discuss
ed in detail. (C) 2000 Academic Press.