The first O-NO bond energy scale in solution: Heterolytic and homolytic cleavage enthalpies of O-nitrosyl carboxylate compounds

Authors
Xian, M Zhu, XQ Lu, JM Wen, Z Cheng, JP
Citation
M. Xian et al., The first O-NO bond energy scale in solution: Heterolytic and homolytic cleavage enthalpies of O-nitrosyl carboxylate compounds, ORG LETT, 2(3), 2000, pp. 265-268
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
3
Year of publication
2000
Pages
265 - 268
Database
ISI
SICI code
1523-7060(20000210)2:3<265:TFOBES>2.0.ZU;2-Q
Abstract
[GRAPHICS] The first series of O-NO bond dissociation enthalpies was determined in sol ution for eight O-nitrosyl carboxylate compounds by direct titration calori metry with a thermodynamic cycle. The derived bond energy data may serve as a quantitative guide to predict the NO binding and releasing abilities of the related amino acids.