Application of olefin cross-metathesis to organometallics. Synthesis of unsaturated ferrocenyl alcohols and ketones

Citation
H. Seshadri et Cj. Lovely, Application of olefin cross-metathesis to organometallics. Synthesis of unsaturated ferrocenyl alcohols and ketones, ORG LETT, 2(3), 2000, pp. 327-330
Citations number
40
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
3
Year of publication
2000
Pages
327 - 330
Database
ISI
SICI code
1523-7060(20000210)2:3<327:AOOCTO>2.0.ZU;2-L
Abstract
[GRAPHICS] The application of olefin cross metathesis to terminally unsaturated alpha- hydroxy- and alpha-ketoferrocenes is reported, Both substrates provided the terminally functionalized olefins in moderate to good yield. These example s represent the first cases of cross metathesis of substrates containing an organometallic functional group.