We have developed a perturbation formalism to compute the image potential f
or a point charge placed near an interface separating two media of differen
t dielectric constants. By using the Green's identity, the volume integral
equation is cast into a surface integral equation; thus, it greatly simplif
ies numerical solutions and yields accurate results for interfaces of arbit
rary shape. The integral equation is solved numerically and the image poten
tial is obtained for a periodic interface. (C) 2000 Elsevier Science B.V. A
il rights reserved.