ELECTRON-MICROSCOPY OF IRON-OXIDES AND IMPLICATIONS FOR THE ORIGIN OFMAGNETIZATIONS AND ROCK MAGNETIC-PROPERTIES OF BANDED SERIES ROCKS OFTHE STILLWATER COMPLEX, MONTANA
Wx. Xu et al., ELECTRON-MICROSCOPY OF IRON-OXIDES AND IMPLICATIONS FOR THE ORIGIN OFMAGNETIZATIONS AND ROCK MAGNETIC-PROPERTIES OF BANDED SERIES ROCKS OFTHE STILLWATER COMPLEX, MONTANA, J GEO R-SOL, 102(B6), 1997, pp. 12139-12157
The origins of multiple magnetizations of the Archean Stillwater Compl
ex have been investigated through scanning electron microscopy and sca
nning transmission electron microscopy observations of mineralogical r
elations, using representative samples from nine sites in mafic Banded
series rocks. On the basis of directional grouping and demagnetizatio
n behavior, three magnetizations (here labeled A, B, and C) have been
recognized. The natural remanent magnetizaton (NRM) is typically domin
ated by only one of these magnetizations and multicomponent behavior i
n individual specimens is rare. The A remanence resides in magnetic gr
ains of high median destructive fields and high, discrete laboratory u
nblocking temperatures and is inferred to be a primary thermoremanent
magnetization, of circa 2.71 Ga age. The B and C magnetizations, of lo
wer median destructive fields and more distributed unblocking temperat
ures, are inferred to be secondary and related to alteration, includin
g serpentinization, involving limited, moderate to low-temperature flu
id interaction, perhaps in response to thermotectonic events (e.g., ma
fic dike emplacement). Samples with NRM dominated by the A magnetizati
on contain titanium-free magnetite needles (width < 1 mu m and maximum
dimension between about 2 and 50 mu m) with preferred orientations in
cumulus plagioclase crystals; these oxides are interpreted to have fo
rmed during initial crystallization of cumulus phases. In samples cont
aining only B or C magnetizations, such needles are absent in cumulus
plagioclase, whereas secondary Fe-bearing silicates, particularly zois
ite and chlorite, are conspicuous. The samples dominated by the B or C
magnetizations contain anhedral low-chromian magnetite (FeCr2-xFexO4,
1.5 < x < 2.0) along fractures in both cumulus plagioclase and pyroxe
ne and in zones of more pervasive alteration of pyroxenes. The paragen
esis of these oxides is consistent with an origin related to hydrother
mal alteration. Hysteresis data show that plagioclase crystals contain
ing magnetite needles have higher remanent coercivities (H-cr = 60 to
100 mT), whereas plagioclase crystals with anhedral chromian magnetite
have remanent coercivities less than 60 mT, consistent with their alt
ernating field response. Because oxygen isotope data show no indicatio
n of appreciable alteration of host plagioclase, we infer that the abs
ence of magnetite needles and their associated A magnetization are cau
sed by selective alteration of the magnetite needles to nonmagnetic ph
ases in the remagnetized gabbros. In this case, rock magnetic and pale
omagnetic data appear to be higher resolution indicators of fluid/rock
interaction than the stable isotope data. Anhedral chromian magnetite
precipitated during hydrothermal alteration and therefore carries sec
ondary magnetizations.