The response of Sc and alpha-ScHx, systems (0 less than or equal to x less
than or equal to 0.25) to the implantation of positive muons, i.e., light H
isotopes, has been studied by mu(+)SR spectroscopy in high and low transve
rse magnetic field, and in zero field (ZF). The investigation covered a tem
perature range from 300 K down to 2 K, for various orientations of the sing
le-crystal samples with respect to the field or initial mu(+) polarization.
Below 30 K the positive muons occupy, in pure Sc, a localized "fast-tunnel
ing" state, extending over two adjacent, interstitial-tetrahedral (T) sites
above and below the ab-atomic plane of the hcp lattice. In alpha-ScHx, a f
raction of the muons stays in this tunneling state, while for the other par
t, the muons pair with a H atom, to form the analog of the T-pair state H-S
c-H aligned along the c axis, specific to the alpha* phase. The electric-fi
eld gradients, of muonic as well as intrinsic-crystalline origin, acting on
the nuclei near the mu(+) influence the results at low and zero magnetic f
ields. Their characteristics and the H-concentration dependences are evalua
ted. For the ZF-data analysis a newly developed uniaxial version of the Kub
o-Toyabe formula was applied. Above 30 K the long-range diffusion of positi
ve muons becomes noticeable; a two-state model explains very well the data.
It assumes the mu(+) to be, alternatively, in a state of free diffusion be
tween localized-tunneling states or in a mu(+)-Sc-H trap. The model describ
es the repeated mu(+)-capture and release processes with three characterist
ic correlation times, which follow Arrhenius laws. The parameters, e.g., ac
tivation energies and preexponential factors, are compared to the parameter
s of the H and D dynamics in alpha-ScH(D)(x). From mu SR measurements in a
deuterated sample (alpha-ScD0.10) one infers very similar behaviors of the
mu(+) in D and H solid solutions in the Sc host.