We report the temperature dependence of the magnetic anisotropy in both com
pressive and tensile strained films of Pr0.67Sr0.33MnO3 (PSMO). Compressive
strain induced by growth on LaAlO3 (LAO) substrates results in a spontaneo
us out-of-plane magnetization, while tensile strain (grown on SrTiO3) resul
ts in in-plane magnetization. The coefficient of linear proportionality bet
ween the magnetic anisotropy energy and the tetragonal strain for both comp
ressive and tensile strained PSMO films is larger than that found previousl
y in strained La0.67Ca0.33MnO3 films. From the data, we estimate a 20 unit-
cell magnetic domain wall width for PSMO/ LAG. Scattering from such a narro
w domain wall could produce a potentially significant contribution to the r
esistivity.