Reflectivity spectra of new organic metal (BEDO-TTF)(5)[CsHg( SCN)(4)](2)

Citation
Rm. Vlasova et al., Reflectivity spectra of new organic metal (BEDO-TTF)(5)[CsHg( SCN)(4)](2), PHYS SOL ST, 42(1), 2000, pp. 4-10
Citations number
19
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICS OF THE SOLID STATE
ISSN journal
10637834 → ACNP
Volume
42
Issue
1
Year of publication
2000
Pages
4 - 10
Database
ISI
SICI code
1063-7834(2000)42:1<4:RSONOM>2.0.ZU;2-P
Abstract
The polarized reflectivity and optical conductivity spectra of microcrystal s of the new organic conductor (BEDO-TTF)(5)[CsHg(SCN)(4)](2) based on the donor molecule bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) have been st udied in the spectral ranges 600-6500 and 9000-40000 cm(-1) at 300 K for th ree principal lattice directions. The optical evidence for the quasi-two-di mensional character of the conducting electronic system is obtained. The co nclusion is made that the studied crystal is the quasi-two-dimensional semi metal with overlapping electron energy bands. The basic parameters of the e lectronic system of the crystal are determined in the framework of the Drud e model. It is found that the allowed electron energy bands of the crystal are somewhat narrower than those of the previously studied structurally all ied superconductor based on the same molecule. The features of vibrational structure are identified in the sigma(omega) spectra for the specified thre e polarizations. (C) 2000 MAIK "Nauka/Interperiodica".