An X-ray diffraction study is reported of the symmetry in the spatial distr
ibution of thermal vibrations of Cu2+, Gd3+, and Pr3+ ions in Gd2CuO4 and P
r2CuO4 crystals. An analysis of the pattern of the angular thermal-vibratio
n amplitude distribution obtained experimentally at different temperatures
allows a conclusion about the character of the local Jahn-Teller effect for
the Cu2+ ions, structural phase transitions, and the orbital ground state
of the Cu2+ ions. (C) 2000 MAIK "Nauka/Interperiodica".