Spontaneous phase transition from relaxor to macrodomain ferroelectric state in single-crystal PbSc0.5Nb0.5O3-BaSc0.5Nb0.5O3 solid solutions

Citation
Ip. Raevskii et al., Spontaneous phase transition from relaxor to macrodomain ferroelectric state in single-crystal PbSc0.5Nb0.5O3-BaSc0.5Nb0.5O3 solid solutions, PHYS SOL ST, 42(1), 2000, pp. 161-164
Citations number
15
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICS OF THE SOLID STATE
ISSN journal
10637834 → ACNP
Volume
42
Issue
1
Year of publication
2000
Pages
161 - 164
Database
ISI
SICI code
1063-7834(2000)42:1<161:SPTFRT>2.0.ZU;2-C
Abstract
The cooling of Pb1-xBaxSc0.5Nb0.5O3 solid solutions with x less than or equ al to 0.04 leads to a spontaneous transition from a relaxor to a macrodomai n ferroelectric state, accompanied by anomalous variation of the dielectric and optical properties of the material. As the barium content in the syste m increases, the relaxor state becomes more stable and eventually "freezes" at x approximate to 0.05. The crystals with x = 0.06 exhibited the appeara nce of a macrodomain ferroelectric phase induced both by an external electr ic field with a strength of 1.5 kV/cm and by an internal electric field for med in the course of dielectric aging. (C) 2000 MAIK "Nauka/Interperiodica" .