The synthesis, spectroscopic characterization, crystal and molecular structure of [ReBr3(NO)(dppe)](0.60)[ReBr4(dppe)](0.40)

Authors
Dziegielewski, JO Machura, B Malecki, J Bartczak, TJ Czurak, W
Citation
Jo. Dziegielewski et al., The synthesis, spectroscopic characterization, crystal and molecular structure of [ReBr3(NO)(dppe)](0.60)[ReBr4(dppe)](0.40), POL J CHEM, 74(2), 2000, pp. 191-198
Citations number
21
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
74
Issue
2
Year of publication
2000
Pages
191 - 198
Database
ISI
SICI code
0137-5083(200002)74:2<191:TSSCCA>2.0.ZU;2-9
Abstract
[ReOBr3(dppe)] (where dppe denotes Ph2PCH2CH2PPh2) reacts with gaseous nitr ic oxide in the presence of an excess of flee PPh3 to give [ReBr3(NO)(dppe) ](0.60)[ReBr4(dppe)](0.40), characterized by X-ray crystallography, IR, UV- Vis, and magnetochemical measurements. The complex is a paramagnetic compou nd with magnetic moment 2.54 MB.