Production of levulinic acid and use as a platform chemical for derived products

Citation
Jj. Bozell et al., Production of levulinic acid and use as a platform chemical for derived products, RESOUR CON, 28(3-4), 2000, pp. 227-239
Citations number
86
Categorie Soggetti
Environment/Ecology,"Environmental Engineering & Energy
Journal title
RESOURCES CONSERVATION AND RECYCLING
ISSN journal
09213449 → ACNP
Volume
28
Issue
3-4
Year of publication
2000
Pages
227 - 239
Database
ISI
SICI code
0921-3449(200002)28:3-4<227:POLAAU>2.0.ZU;2-6
Abstract
Levulinic acid (LA) can be produced cost effectively and in high yield from renewable feedstocks in a new industrial process. The technology is being demonstrated on a I ton/day scale at a facility in South Glens Falls, New Y ork. Low cost LA can be used as a platform chemical for the production of a wide range of value-added products. This research has demonstrated that LA can be converted to methyltetrahydrofuran (MTHF), a solvent and fuel exten der. MTHF is produced in >80% molar yield via a single stage catalytic hydr ogenation process. A new preparation of delta-aminolevulinic acid (DALA), a broad spectrum herbicide, from LA has also been developed. Each step in th is new process proceeds in high (> 80%) yield and affords DALA (as the hydr ochloride salt) in > 90% purity, giving a process that could be commerciall y viable. LA is also being investigated as a starting material for the prod uction of diphenolic acid (DPA), a direct replacement for bisphenol A. (C) 2000 ACEEE Published by Elsevier Science B.V. All rights reserved.