Remote chiral induction in the thio-Claisen rearrangement of bicyclic thiolactams

Authors
Watson, DJ Lawrence, CM Meyers, AI
Citation
Dj. Watson et al., Remote chiral induction in the thio-Claisen rearrangement of bicyclic thiolactams, TETRAHEDR L, 41(6), 2000, pp. 815-818
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
6
Year of publication
2000
Pages
815 - 818
Database
ISI
SICI code
0040-4039(20000205)41:6<815:RCIITT>2.0.ZU;2-I
Abstract
A remote steric effect in the bicyclic lactam oxazolidine ring has been sho wn to affect the stereochemical outcome in the thio-Claisen rearrangement t aking place in the piperidone ring. (C) 2000 Elsevier Science Ltd. All righ ts reserved.