Asymmetric Strecker reactions of ketimines catalysed by titanium-based complexes

Authors
Byrne, JJ Chavarot, M Chavant, PY Vallee, Y
Citation
Jj. Byrne et al., Asymmetric Strecker reactions of ketimines catalysed by titanium-based complexes, TETRAHEDR L, 41(6), 2000, pp. 873-876
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
6
Year of publication
2000
Pages
873 - 876
Database
ISI
SICI code
0040-4039(20000205)41:6<873:ASROKC>2.0.ZU;2-4
Abstract
The asymmetric addition of TMSCN to a ketimine has been achieved by use of catalytic quantities of chiral titanium(IV) complexes. Fast conversions tog ether with enantiomeric excesses as high as 59% have been achieved. (C) 200 0 Elsevier Science Ltd. All rights reserved.