T. Yonemoto et al., CONTINUOUS SYNTHESIS OF TITANIUM-DIOXIDE FINE PARTICLES USING A SLUG FLOW AGING TUBE REACTOR, Chemical engineering research & design, 75(A4), 1997, pp. 413-419
A continuous reactor system for titanium dioxide fine particle synthes
is has been proposed, in which a packed bed for the nucleation of fine
particles was connected in series with a slug flow ageing tube for gr
owth of the particles. By injection of nitrogen gas into the inlet of
the ageing tube, the continuous liquid feed was separated into small p
ortions so that slug flow was formed. Spherical unagglomerated fine pa
rticles of titanium dioxide were obtained using this reactor system, a
nd the effectiveness of using slug flow was elucidated. The effects of
some operation variables such as liquid flow rate in the ageing tube
and tube diameter were also examined. The particles obtained under the
slug flow condition had narrower particle size distribution than thos
e under a laminar flow condition at any flow rate. Particle geometric
standard derivation (GSD) was found to be as small as that obtained in
a batch process. No quality difference in particle GSD exists between
ageing tubes of 2 mm i.d. and 3 mm i.d. for the slug flow. Chronomal
analysis assuming diffusion-controlled growth was applied and was foun
d to be effective for simulating a continuous particle synthesis proce
ss of titanium dioxide.