FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia

The sorption of 2,2'-biquinoline onto natural and ion-exchanged montmorillo nite (Fe-, Co- or Cu-montmorillonite) and saponite from Anatolia have been investigated using FT-IR and FT-Raman Spectrometry. The intercalation of 2, 2'-biquinoline within natural and ion-exchanged montmorillonite and saponit e has been shown by X-ray diffraction to increase the interlayer spacing, T he difference of basal spacing of air-dried clays and biquinoline treated o nes shows monolayer arrangement. Raman spectroscopy was particularly useful for investigation of clay-organic interaction. Vibrational spectroscopy in dicates that intercalated 2,2'-biquinoline molecules are coordinated to exc hangeable cations (directly and indirectly through water bridges) and/or Le wis acid sites or as bidentate ligand. (C) 2000 Elsevier Science B.V. All r ights reserved.