mer-[Re(py)(3)FI2], a mixed fluoro iodo pyridine complex of trivalent rhenium

Authors
Holzbock, J Sawodny, W Thewalt, U
Citation
J. Holzbock et al., mer-[Re(py)(3)FI2], a mixed fluoro iodo pyridine complex of trivalent rhenium, Z ANORG A C, 626(2), 2000, pp. 321-322
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
2
Year of publication
2000
Pages
321 - 322
Database
ISI
SICI code
0044-2313(200002)626:2<321:MAMFIP>2.0.ZU;2-2
Abstract
The title compound has been prepared from ReI3, TI(OC2H5) and benzoylfluori de in pyridine. The substance was characterized by elemental analysis and b y a crystal structure determination. Space group P (1) over bar, Z = 2, lat tice dimensions at 20 degrees C: a = 8.266(3), b = 8.710(3), c = 13.707(4) Angstrom, alpha = 100.55(2), beta = 103.87(2), gamma = 100.99(2)degrees. Th e Re atom is nearly octahedrally coordinated and the pyridine ligands are i n mer positions.