The growth of the layered chalcogenide GaSe on cleaved GaAs(110) surfaces w
as investigated with photoemission and low-energy electron diffraction (LEE
D). GaSe films grow with their c axis perpendicular to the GaAs(110) surfac
e. LEED patterns after initial film growth are a superposition of rectangul
ar GaAs:Se spots and two hexagonal domains rotated by +/- 5 degrees with re
spect to the GaAs [001] axis. At higher film thickness a hexagonal LEED pat
tern with GaSe [120] parallel to GaAs [001] is obtained. (C) 2000 American
Institute of Physics. [S0003-6951(00)00709-9].