Preparation and structure of [RhCl(nbd)(dmap)] (nbd = bicyclo[2.2.1]hepta-2,5-diene; dmap = 4-(N,N-dimethylamino)pyridine)

Authors
Takenaka, Y Osakada, K
Citation
Y. Takenaka et K. Osakada, Preparation and structure of [RhCl(nbd)(dmap)] (nbd = bicyclo[2.2.1]hepta-2,5-diene; dmap = 4-(N,N-dimethylamino)pyridine), B CHEM S J, 73(1), 2000, pp. 129-130
Citations number
22
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
73
Issue
1
Year of publication
2000
Pages
129 - 130
Database
ISI
SICI code
0009-2673(200001)73:1<129:PASO[(>2.0.ZU;2-Q
Abstract
4-(N,N-Dimethylamino)pyridine (dmap) reacts with [{RhCl(nbd)}(2)] to give [ RhCl(nbd)(dmap)] (1), which was characterized by X-ray crystallography and NMR spectroscopy. The crystal structure and dynamic behavior of the molecul e in solution are compared with those of [RhCl(nbd)(PPh3)] (2).