On the role of planar chirality: a tunable enantioselectivity in palladium-catalyzed allylic alkylation with planar chiral 1,1 '-P,N-ferrocene ligands

Authors
Deng, WP Hou, XL Dai, LX Yu, YH Xia, W
Citation
Wp. Deng et al., On the role of planar chirality: a tunable enantioselectivity in palladium-catalyzed allylic alkylation with planar chiral 1,1 '-P,N-ferrocene ligands, CHEM COMMUN, (4), 2000, pp. 285-286
Citations number
27
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
2000
Pages
285 - 286
Database
ISI
SICI code
1359-7345(2000):4<285:OTROPC>2.0.ZU;2-7
Abstract
A series of planar chiral 1,1'-P,N-2'-substituted ferrocene ligands 9-12 an d 16, prepared with diastereopurity > 99:1, have been used to examine the r ole of planar chirality, and significant effects on enantioselectivity as w ell as the control of absolute configuration in palladium-catalyzed allylic alkylation as a model reaction were observed.