Two different [1,3]-B shifts in phenalenyl(dipropyl)borane

Authors
Tok, OL Gridnev, ID Korobach, EM Bubnov, YN
Citation
Ol. Tok et al., Two different [1,3]-B shifts in phenalenyl(dipropyl)borane, CHEM COMMUN, (4), 2000, pp. 311-312
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
2000
Pages
311 - 312
Database
ISI
SICI code
1359-7345(2000):4<311:TD[SIP>2.0.ZU;2-K
Abstract
Both possible [1,3]-B sigmatropic shifts are observed in the title compound ; benzylic rearrangement to position 9 is much faster than allylic migratio n to position 3.