In order to quantify deep-water exchange in the Caspian Sea, the world's la
rgest inland water body, water samples were analyzed for the transient trac
ers H-3, He-3, He-4, CFC-11, CFC-12 and atmospheric noble gases. Measuremen
ts of temperature, salinity (calculated from conductivity for the ionic com
position of Caspian Sea water), and dissolved oxygen were employed to inves
tigate the processes responsible for deep-water renewal. The Caspian Sea co
nsists of two deep basins, the southern and central basins, separated by a
sill, and a shallow northern basin. The deep water (below 200 m) accounts f
or almost 60% of the total water mass. Below 200 m the concentrations of 3H
and 3He are much lower in the southern basin than at the same depths in th
e central basin, but this is not the case for either of the CFCs. However,
apparent water ages calculated from H-3-He-3 and from CFC-12 concentrations
are the same for the deep water of the southern and central basins, and yi
eld deep-water exchange rates of approximately 7% per year for each of the
two basins. This implies volume fluxes across the 200-m level of about 2220
km(3) yr(-1) within the southern basin and 770 km(3) yr(-1) within the cen
tral basin. Based on the apparent water ages, the oxygen depletion in the d
eep water is estimated to be about 0.35 mg l(-1) yr(-1). The processes resp
onsible for deep-water exchange have not yet been identified conclusively.
However, vertical temperature and salinity gradients observed during two ex
peditions, in September 1995 and 1996, suggest that within the southern and
central basins large-scale convection cannot be triggered by seasonal cool
ing alone, but requires the surface water to be cold/saline or to contain h
igh suspended sediment loads. In the central basin the increase in salinity
occurring during ice formation in early winter is possibly sufficient to c
ause convection. In late summer, the horizontal transport of water from the
upper 170 m of the central basin into the southern basin results in mixing
down to 400 m. In winter this process might result in convection down to t
he maximum depth. Alternatively, the data are also consistent with the hypo
thesis that rare events cause large-scale convection down to the maximum de
pth in the southern and in the central basin simultaneously, followed by sl
ight mixing that mainly affects only the top 500 m. According to apparent w
ater ages from below 500 m, the last such major mixing event could have occ
urred in 1976 shortly before the water level of the Caspian Sea began to ri
se. (C) 2000 Elsevier Science Ltd. All rights reserved.