We report the discovery of singly ionized chlorine in the Io plasma torus t
hrough the detection of emission at 857.9 nm. The 40 Rayleigh peal; intensi
ty at 857.9 nm corresponds to a Cl+ abundance of 2+/-0.5% relative to all i
ons. Since Cl+ probably originates at Io, Io's atmosphere must have the hig
hest proportion of chlorine of any solar system body. While Cl+ plays only
a minor role in torus physics, the presence of chlorine in Io's atmosphere,
surface, and interior has more profound implications. Salt as a solid or g
as is probably an important source of both Na and Cl in Io's vicinity.