NEW POLY(BISMALEIMIDE-ETHER)S CONTAINING FUNCTIONAL PENDANT CARBOXYLIC GROUPS

Citation
C. Hulubei et al., NEW POLY(BISMALEIMIDE-ETHER)S CONTAINING FUNCTIONAL PENDANT CARBOXYLIC GROUPS, Journal of macromolecular science. Pure and applied chemistry, A34(6), 1997, pp. 1085-1095
Citations number
14
Categorie Soggetti
Polymer Sciences
ISSN journal
10601325
Volume
A34
Issue
6
Year of publication
1997
Pages
1085 - 1095
Database
ISI
SICI code
1060-1325(1997)A34:6<1085:NPCFPC>2.0.ZU;2-1
Abstract
New poly(bismaleimide-ether)s with functional pendant groups were synt hesized by Michael addition polymerization of two monomers with functi onality f>2 (DL tartaric acid and methylene-5,5'disalicylic acid) to v arious bismaleimides with flexible groups (N,N'-4,4'-diphenylmethanebi smaleimide, N,N'-4,4'-diphenyletherbismaleimide and N,N'-4,4'-dibenzyl bismaleimide). The polymerization occurred in solution, through the ad dition of the OH groups to the C=C double bond of the maleimide rings. The polymers were obtained in good yields and they were characterized by elemental analysis, IR and H-1 NMR spectra, thermogravimetric anal ysis and viscozimetry.