Ms. Child et Wl. Glab, Multichannel quantum defect analysis of the double resonance photoionization series of H2O, J CHEM PHYS, 112(8), 2000, pp. 3754-3765
A new analysis is presented of the recent photoionization spectrum of H2O,
excited by double resonance via several rotational sublevels of the (100) v
ibrational level of the C(B-1(1)) state. Evidence for a previously unsuspec
ted strong f series indicates significant d orbital contamination of the no
minal p orbital in the intermediate state. This is the first report of an f
series in the Rydberg state of any asymmetric top. Previous d series analy
ses of single-photon photoionization spectra terminating on the (100) level
of H2O+ are also corrected and extended to a wider range of excited rotati
onal electronic states. The d series appears to contain absent lines, indic
ative of predissociation. Some lines remain unassigned, but there is no sys
tematic evidence of either s or p series. (C) 2000 American Institute of Ph
ysics. [S0021-9606(00)01408-2].