Synthesis of dioxazaborocines from N,N '-alkylbridged-bis(bis(2-hydroxybenzyl)aminomethyl)amines

Citation
Pd. Woodgate et al., Synthesis of dioxazaborocines from N,N '-alkylbridged-bis(bis(2-hydroxybenzyl)aminomethyl)amines, J ORGMET CH, 595(2), 2000, pp. 215-223
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
595
Issue
2
Year of publication
2000
Pages
215 - 223
Database
ISI
SICI code
0022-328X(20000215)595:2<215:SODFN'>2.0.ZU;2-U
Abstract
The aminoalkylation of 2H-1,3-naphthoxazines by phenols has been used to pr epare some tripodal amines. A series of these ligands were coordinated to b oron, giving dioxazaborocines. The X-ray crystal structures of two dioxazab orocines are reported. These compounds are capable of releasing berate ions in vivo and are therefore potentially biologically active. (C) 2000 Elsevi er Science S.A. All rights reserved.