A new host 2,3,6,7,10,11-hexahydroxy triphenylene which forms chiral inclusion crystalline lattice: X-ray structural study of the chiral crystalline lattice

Authors
Toda, F Tanaka, K Matsumoto, T Nakai, T Miyahara, I Hirotsu, K
Citation
F. Toda et al., A new host 2,3,6,7,10,11-hexahydroxy triphenylene which forms chiral inclusion crystalline lattice: X-ray structural study of the chiral crystalline lattice, J PHYS ORG, 13(1), 2000, pp. 39-45
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
ISSN journal
08943230 → ACNP
Volume
13
Issue
1
Year of publication
2000
Pages
39 - 45
Database
ISI
SICI code
0894-3230(200001)13:1<39:ANH2TW>2.0.ZU;2-6
Abstract
The title compound was found to form an inclusion complex crystal with vari ous kinds of guests. It was also found that crystalline lattice of some inc lusion complex is chiral. By an enantioselective inclusion complexation in the chiral lattice, the racemic guest was resolved. The chiral crystalline lattice was studied by X-ray analysis. Solid-state synthesis of the title h ost compound is also described. Copyright (C) 2000 John Wiley & Sons, Ltd.