Wj. Jackson et al., An X-ray absorption spectroscopic study at the mercury L-III edge on phenylmercury(II) oxygen species, J CHEM S DA, (4), 2000, pp. 491-498
Citations number
41
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
The X-ray absorption spectra of the reference and model compounds HgCl2, Ph
HgCl, PhHgOAc and [(PhHg)(2)OH][BF4]. H2O have been analysed in both the XA
NES and EXAFS regions, and the technique was extended to determine the stru
ctures of (PhHg)(2)O, PhHgOH, and the basic salts PhHgOH . PhHgNO3 and PhHg
OH .(PhHg)(2)SO4, which were previously structurally uncharacterised. Resul
ts indicate that (PhHg)(2)O is a molecular species with Hg-O-Hg 135 degrees
, while PhHgOH contains the [(PhHg)(2)OH](+) cation and is better formulate
d as [(PhHg)(2)OH]OH. The same cation is also featured in the two basic sal
ts. Electrospray mass spectral studies of PhHgOH in aqueous solutions show
that [PhHgOH2](+), [(PhHg)(2)OH](+) and [(PhHg)(3)O](+) co-exist in solutio
n in a pH-dependent equilibrium.