Grafting ruthenium phthalocyanine on gold and silica: Using apical ligandsas linkers

Citation
V. Huc et al., Grafting ruthenium phthalocyanine on gold and silica: Using apical ligandsas linkers, LANGMUIR, 16(4), 2000, pp. 1770-1776
Citations number
43
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
16
Issue
4
Year of publication
2000
Pages
1770 - 1776
Database
ISI
SICI code
0743-7463(20000222)16:4<1770:GRPOGA>2.0.ZU;2-M
Abstract
Ruthenium phthalocyanines bearing pyridine-4-carboxaldehyde as an axial lig and were synthesized. The carboxaldehyde group of the apical ligand pointin g out from the phthalocyanine ring was used to link the complex to chemical ly modified surfaces. The resulting monolayer was characterized by ellipsom etry, IRRAS, XPS, X-ray reflectivity, and SPM. The grafting of RuPc to the surface is stable.