Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)(2)PH2]Pd and [H2P(CH2)(2)PH2]Pd-2

Authors
Mamaev, VM Gloriozov, IP Simonyan, VV Zernova, EV Myshakin, EM Babin, YV
Citation
Vm. Mamaev et al., Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)(2)PH2]Pd and [H2P(CH2)(2)PH2]Pd-2, MENDELEEV C, (1), 2000, pp. 12-14
Citations number
21
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
1
Year of publication
2000
Pages
12 - 14
Database
ISI
SICI code
0959-9436(2000):1<12:TEITOA>2.0.ZU;2-3
Abstract
In terms of the reaction-path Hamiltonian formalism, the ligand environment has been found to have almost no effect on the activation barrier in the o xidative addition of H-2 to the title complexes (the under-barrier tunnelli ng in the reaction was predominant at T < 230 K).