We have measured the electrical resistivity, the magnetoresistance, the Hal
l effect, and the magnetization in varying temperature ranges between 0.3 a
nd 300 K on single crystals of EuB6, CaB6, and Eu0.8Ca0.2B6. The ferromagne
tic phase transition of EuB6, marked by a sharp peak in the temperature dep
endence of the electrical resistivity p(T) just below 16 K, is shown to be
accompanied by a considerable increase of the effective charge carrier conc
entration n(eff). The overall features of the transport properties of Eu0.8
Ca0.2B6 are similar to those of EuB6. A phase transition at 5.3 K has been
established. However, the increase of n(eff) across this phase transition b
y two orders of magnitude is much more pronounced than in pure EuB6.