Energy distributions of nitrogen atoms (N) in a hollow-cathode planar sputt
ering magnetron were obtained by use of optical emission spectroscopy. A ch
aracteristic line, N I 8216.3 Angstrom, well separated from molecular nitro
gen emission bands, was identified. Jansson's nonlinear spectral deconvolut
ion method, refined by minimization of chi(w)(2), was used to obtain the op
timal deconvolved spectra. These showed nitrogen atom energies from 1 eV to
beyond 500 eV. Based on comparisons with VFTRIM computer code results, it
is proposed that the energetic N's are generated from N-2(+) ions after the
se ions are accelerated through the sheath and dissociatively reflect from
the cathode.