PREPARATION AND X-RAY STRUCTURE OF 4-BRC6H4CNSC(CL)N

Authors
CHIVERS T PARVEZ M ZORICAK P
Citation
T. Chivers et al., PREPARATION AND X-RAY STRUCTURE OF 4-BRC6H4CNSC(CL)N, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(5), 1997, pp. 557-559
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
5
Year of publication
1997
Pages
557 - 559
Database
ISI
SICI code
0932-0776(1997)52:5<557:PAXSO4>2.0.ZU;2-D
Abstract
The title compound was obtained in 82% yield by the intramolecular cyc lization of 4BrC(6)H(4)C(NSCCl3)[N(SiMe3)(2)] in CH2Cl2 at 23 degrees C. It crystallizes in the triclinic system, space group P (1) over bar , a = 7.957(3) Angstrom, b = 10.864(5) Angstrom, c = 5.625(1) Angstrom , alpha = 95.94(3)degrees, beta = 97.79(2)degrees, gamma = 100.72(3)de grees, V = 469.2(3) Angstrom(3), and Z = 2. The bond lengths of the pl anar C2N2S ring indicate partial pi-delocalization.