F. Kirino et al., MAGNETIC-PROPERTIES AND CORROSION-RESISTA NCE OF FE-TA-C SPUTTERED THIN-FILMS PREPARED UNDER ARGON ATMOSPHERE CONTAINING NITROGEN GAS, Nippon Kinzoku Gakkaishi, 61(4), 1997, pp. 358-365
The magnetic properties, the thermal stability, and the corrosion resi
stance of Fe-Ta-C thin films prepared in an atomsphere containing N-2
were studied. As the N-2 content in the sputtering gas is increased, B
s and mu decrease, while He and lambda s increase. A film prepared in
Ar+N-2 (1.5 vol%) has Bs of about 1.4 T, and mu (at 1 MHz) higher than
2000. A film prepared in Ar+N-2 (2 vol%) has He of 80 A/m, and lambda
s of 1.4 x 10(-6). Fe-Ta-C thin films produced in an atomsphere conta
ining N-2 have a high thermal reliability. After thermal treatment at
873 K, the soft magnetic properties of Fe-Ta-C thin film produced in t
he atomsphere containing N-2 did not change, while that of Fe-Ta-C thi
n film produced in pure Ar atomsphere changed, namely, He increased an
d mu decreased. The corrosion resistance was measured by change of Bs.
The value of Bs of the Fe-Ta-C thin film prepared in an atomsphere co
ntainning N-2 did not change after being immersed in pure water for 3.
96 x 10(5) s. Furthermore, this film has a high corrosion resistance i
n pure water with Ar bubbling for 1800 s. However, Bs of Fe-Ta-C thin
film prepared in pure Ar atomsphere decreased to 65% of the initial va
lue. After immersing the Fe-Ta-C thin film prepared in Ar+N-2 (0.5 vol
%) in 0.01 N NaClaq for 3.96 x 10(5) s, Bs decreased to 75% of the ini
tial value, while in the case of Fe-Ta-C thin film prepared in Ar+N-2
(5 vol%), Bs decreased to 95% of the initial Bs.