Asymmetric synthesis of aziridinyl phosphonates using darzens-type reaction of chloromethyl phosphonate to chiral sulfinimines

Authors
Kim, DY Suh, KH Choi, JS Mang, JY Chang, SK
Citation
Dy. Kim et al., Asymmetric synthesis of aziridinyl phosphonates using darzens-type reaction of chloromethyl phosphonate to chiral sulfinimines, SYN COMMUN, 30(1), 2000, pp. 87-95
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
1
Year of publication
2000
Pages
87 - 95
Database
ISI
SICI code
0039-7911(2000)30:1<87:ASOAPU>2.0.ZU;2-Y
Abstract
Darzens-type reaction of chloromethyl phosphonate with (S)-(+)-N-sulfinimin es gave (Ss, 2S, 3R)-diethyl 3-aryl-2-N-(p-toluenesulfinyl)aziridinyl-phosp honate (3) in good yields.