Synthesis of nitronyl- and imino-nitroxide-triradicals interconnected by phenyl ethynyl spacer

Authors
Catala, L Turek, P Le Moigne, J De Cian, A Kyritsakas, N
Citation
L. Catala et al., Synthesis of nitronyl- and imino-nitroxide-triradicals interconnected by phenyl ethynyl spacer, TETRAHEDR L, 41(7), 2000, pp. 1015-1018
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
7
Year of publication
2000
Pages
1015 - 1018
Database
ISI
SICI code
0040-4039(20000212)41:7<1015:SONAII>2.0.ZU;2-#
Abstract
The design and synthesis, as well as solid state and ESR characterisation o f three new triradicals based on phenyl ethynyl backbone bearing nitronyl-n itroxide and imino-nitroxide groups, are reported. The synthesis of these c ompounds was based on palladium-coupling reactions between alkynyl and brom o derivatives. An ESR study showed magnetic interactions between the radica ls through the phenyl ethynyl-coupling unit in solution. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.