Sequential deposition of Mn on a polycrystalline Al layer at 523-573 K was
found to result in an anomalous icosahedral (i) Al-Mn phase, characterized
by alterations of intensity- and linewidth ratios. The anomalies suggest a
non-equilibrium atom distribution, related to the limited diffusion of Al t
hrough the already-formed layer of i-AlMn. The activation energy of Al diff
usion was inferred from X-ray diffraction (XRD) data taken for different de
position temperatures. (C) 2000 Elsevier Science S.A. All rights reserved.