J. Herion et al., AFM AND STM INVESTIGATIONS OF HYDROGENATED AMORPHOUS-SILICON - TOPOGRAPHY AND BARRIER HEIGHTS, Fresenius' journal of analytical chemistry, 358(1-2), 1997, pp. 338-340
As-grown films of hydrogenated amorphous silicon (a-Si:H, highly phosp
horous-doped) were investigated by atomic force microscopy (AFM) and s
canning tunneling mi microscopy (STM). Hills up to 10 nm in height and
10 to 20 nm in diameter have been observed by AFM. By using STM in a
new high-sensitivity mode, (1) atomically smooth areas (rough ness abo
ut 0.3 Angstrom rms) which occur at the top of the hills, (2) subnanom
eter structures several Angstrom in height which cover large parts of
the surface have been identified. Simultaneous measurements of the loc
al apparent barrier heights (LABH) show a clear correlation to the top
ography. Areas showing subnanometer structures have always low LABHs w
hile the highest values of the LABH occur on the smooth areas.