Transcrystallisation in natural fibre reinforced polypropylene

Citation
I. Mildner et Ak. Bledzki, Transcrystallisation in natural fibre reinforced polypropylene, ANGEW MAKRO, 272, 1999, pp. 27-33
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ANGEWANDTE MAKROMOLEKULARE CHEMIE
ISSN journal
00033146 → ACNP
Volume
272
Year of publication
1999
Pages
27 - 33
Database
ISI
SICI code
0003-3146(199912)272:<27:TINFRP>2.0.ZU;2-N
Abstract
The influence of thermal conditions (recrystallisation temperature, cooling rate) as well as of different fibre treatments on the crystallisation of p olypropylene was examined by using melting-microscopic analysis. The result s of these investigations show that the nucleation density of untreated and MAH-grafted polypropylene treated jute fibres is higher in comparison with alkalised jute fibres because of differences in the chemical composition a nd physical properties of the fibre surface. With increasing recrystallisat ion temperature the maximum of transcrystalline layer thickness was shifted to higher crystallisation times. Experimental data of this coherence were successfully fitted by using a simple Arrhenius-type relationship. Regardin g non-isothermal crystallisation, the beginning of transcrystallisation was shifted, as expected, to lower temperatures with increasing cooling rate.