Offset dependence of homonuclear Hartmann-Hahn transfer based on residual dipolar couplings in solution state NMR

Authors
Kramer, F Luy, B Glaser, SJ
Citation
F. Kramer et al., Offset dependence of homonuclear Hartmann-Hahn transfer based on residual dipolar couplings in solution state NMR, APPL MAGN R, 17(2-3), 1999, pp. 173-187
Citations number
28
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
APPLIED MAGNETIC RESONANCE
ISSN journal
09379347 → ACNP
Volume
17
Issue
2-3
Year of publication
1999
Pages
173 - 187
Database
ISI
SICI code
0937-9347(1999)17:2-3<173:ODOHHT>2.0.ZU;2-T
Abstract
The offset dependence of homonuclear Hartmann-Hahn transfer is markedly dif ferent if a given multiple-pulse sequence is applied to dipolar coupled spi ns or to isotropically coupled spins. The different offset dependence of th e transfer efficiency is studied by numerical simulations of a multiple-pul se sequence and by the analytical treatment of a simple model experiment.