We report a quantitative investigation on the efficiency of the steam laser
cleaning process using ns and ps pulses. Well-characterized polymer partic
les with a diameter of 800 nm dispersed on commercial Si wafers were chosen
as a modeling contaminant system. As a result of our investigation, we sho
w for the first time the feasibility of performing efficient steam laser cl
eaning with ps laser pulses and compare the achieved efficiency with the on
e obtained for ns pulses. For ns pulses, we found a cleaning fluence thresh
old of 50 mJ/cm(2) that is independent of the pulse durations (2.5 ns and 8
ns) and the wavelengths (532 nm and 583 nm) used. The application of ps pu
lses (FWHM = 30ps, lambda = 583 nm) lowered this threshold to 20mJ/cm(2). B
oth cleaning thresholds are far below the melting thresholds for these lase
r parameters. Cleaning efficiencies > 90% were reached for both pulse durat
ions.