We report on prompt emission of fast electrons occurring during nanosecond
excimer laser ablation of aluminum targets in vacuum. We have measured both
the kinetic energy distribution and the energy-integrated time-of-flight d
istribution of these electrons, in the fluence range 1-10 Jcm(-2). Moreover
, at higher laser fluences, the yield of prompt electrons and the most prob
able kinetic energy as a function of the laser pulse fluence have also been
obtained by charge collection and time-of-flight measurements. The experim
ental data show that the prompt electrons are produced during the laser pul
se as a consequence of two-photon processes, and that space-charge effects
influence the photoemitted electron kinetic energy leading to prompt electr
ons with most probable kinetic energies up to approximate to 15 eV, in the
investigated fluence range.