Formation mechanisms of atomic and oxide ions in a plume (laser-induced pla
sma) produced by the laser ablation of a YBa2Cu3O7-x (YBCO) target was stud
ied by time-of-flight (TOF) analysis. The dependence of the TOF spectra on
the laser wavelengths (266 nm and 1064 nm) was examined to elucidate photoc
hemical phenomena in the plume. Significant changes in the relative enrichm
ent of metal oxide and oxygen ions as well as their TOF distributions were
observed by the injection of an oxygen jet to the plume, which induces reac
tive scattering of the YBCO plume and the oxygen jet.