E. Richter et al., HYDROGEN IN CARBON-DOPED GAAS BASE LAYER OF GAINP GAAS HETEROJUNCTIONBIPOLAR-TRANSISTORS/, Materials science & engineering. B, Solid-state materials for advanced technology, 44(1-3), 1997, pp. 337-340
Hydrogen incorporation into heavily carbon-doped GaAs grown by metal-o
rganic vapour phase epitaxy using carbon tetrabromide (CBr4) has been
studied. In the base layer of as-grown GaInP/GaAs heterojunction bipol
ar transistors (HBTs), about 20% of the carbon accepters are found to
be passivated by hydrogen. The outdiffusion of this hydrogen during an
ex situ annealing at 450 degrees C in nitrogen, which is effective fo
r carbon-doped single layers, is blocked by n-type capping layers in H
BTs. An in situ annealing step was found to be suitable to reduce the
acceptor passivation in HBTs to about 10%. (C) 1997 Elsevier Science S
.A.