Enhanced radical delivery from aldoxime esters for EPR and ring closure applications

Authors
McCarroll, AJ Walton, JC
Citation
Aj. Mccarroll et Jc. Walton, Enhanced radical delivery from aldoxime esters for EPR and ring closure applications, CHEM COMMUN, (5), 2000, pp. 351-352
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
5
Year of publication
2000
Pages
351 - 352
Database
ISI
SICI code
1359-7345(2000):5<351:ERDFAE>2.0.ZU;2-A
Abstract
Arylmethaniminyl and alkyl radicals were generated from di- and tri-methoxy phenyl aldoxime esters, by photolysis in the presence of 4-methoxyacetophen one, and were detected by EPR spectroscopy: good yields of cyclised product s were isolated from suitably unsaturated alkyl substituents.